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Technical Paper

Study on Removal of PM and NOx in Diesel Exhaust by Using DC Corona Discharge

2002-05-06
2002-01-1660
In order to remove the diesel particulate matter (PM) and nitrogen oxides (NOx) from diesel exhaust, the gas is passed through a corona discharge collector for PM and another corona discharge device for NOx oxidation. With the PM collector, PM is accumulated on the central electrode, after that, it is removed by incineration technique. NOx concentration is decreased by oxidation to HNO3. In this study, these corona discharge reactors were coupled for removal of PM and NOx in progression, and attempted to remove these emissions in a slipstream of 14 liters/min of an experimental diesel engine and an actual vehicle, respectively. In case of the experimental test engine, it is found that nearly 100% and 15% of the PM and NOx emissions were removed even at a low input power of 26W (1560 J/L specific energy deposition). In the vehicle tests 1) a PM removal rate of 60% is obtained at an input power of over 40W, 2) a NOx removal rate of 97% is obtained at an input power of over 100W.
Technical Paper

CFD Study of an LPG DI SI Engine for Heavy Duty Vehicles

2002-05-06
2002-01-1648
This work aimed to develop an LPG fueled direct injection SI engine, especially in order to improve the exhaust emission quality while maintaining high thermal efficiency comparable to a conventional engine. In-cylinder direct injection engines developed recently worldwide utilizes the stratified charge formation technique at low load, whereas at high load, a close-to-homogeneous charge is formed. Thus, compared to a conventional port injection engine, a significant improvement of fuel consumption and power can be achieved. To implement such a combustion strategy, the stratification of mixture charge is very important, and an understanding of its combustion process is also inevitably necessary. In this work, a numerical simulation was performed using a CFD code (KIVA-3), where the shape of a combustion chamber, swirl intensity, injection timing and duration, etc. were varied and their effects on the mixture formation and combustion process were investigated.
Technical Paper

The Possibility of Gas to Liquid (GTL) as a Fuel of Direct Injection Diesel Engine

2002-05-06
2002-01-1706
In this study, engine performances and exhaust emissions characteristics of compression ignition engine fueled with GTL were investigated by comparison with diesel fuel. Diesel engine could be operated fueled with GTL without any special modify for the test engine. With the high cetane number of GTL, the ignition lag was shorter, and the combustion started earlier than that of diesel fuel. Brake thermal efficiency operated with GTL increased at middle load conditions due to incomplete combustion emission such as CO and THC were lower than that of diesel fuel operation. NOx emission with GTL was comparable to diesel fuel, and there was a little decrease at high load. With GTL, soot emission was lower than with diesel fuel at above middle load condition. It seemed to be a reason of soot reduction that there was little sulphur contained in GTL.
Technical Paper

Spectroscopic Investigation of the Combustion Process in DME Compression Ignition Engine

2002-05-06
2002-01-1707
For better understanding of the in-cylinder combustion characteristics of DME, combustion radicals of a direct injection DME-Fueled compression ignition engine were observed using a spectroscopic method. In this initial report, the emission intensity of OH, CH, CHO, C2 and NO radicals was measured using a photomultiplier. These radicals could be measured with wavelength resolution (half-width) as about 3.3 nm. OH and CHO radicals appeared first, and then CH radical emission was detected. After that, the combustion radicals were observed using a high-speed image intensified video camera with band-pass filter. All of radicals were able to observe as images with half-width as 6 or about 10 nm. Rich DME leaked from nozzle was burning at the end of combustion. Therefore, the second light emission of C2 radical after the main combustion was observed.
Technical Paper

Atomization Characteristics for Various Ambient Pressure of Dimethyl Ether (DME)

2002-05-06
2002-01-1711
Recently, dimethyl ether (DME) has been attracting much attention as a clean alternative fuel, since the thermal efficiency of DME powered diesel engine is comparable to diesel fuel operation and soot free combustion can be achieved. In this experiment, the effect of ambient pressure on DME spray was investigated with observation of droplet size such as Sauter mean diameter (SMD) by the shadowgraph and image processing method. The higher ambient pressure obstructs the growth of DME spray, therefore faster breakup was occurred, and liquid column was thicker with increasing the ambient pressure. Then engine performances and exhaust emissions characteristics of DME diesel engine were investigated with various compression ratios. The minimum compression ratio for the easy start and stable operation was obtained at compression ratio of about 12.
Technical Paper

Performance and Emissions Characteristics of an LPG Direct Injection Diesel Engines

2002-03-04
2002-01-0869
In this study, performance and emissions characteristics of an LPG direct injection (DI) engine with a rotary distributor pump were examined by using cetane enhanced LPG fuel developed for diesel engines. Results showed that stable engine operation was possible for a wide range of engine loads. Also, engine output power with cetane enhanced LPG was comparable to diesel fuel operation. Exhaust emissions measurements showed NOx and smoke could be reduced with the cetane enhanced LPG fuel. Experimental model vehicle with an in-line plunger pump has received its license plate in June 2000 and started high-speed tests on a test course. It has already been operated more than 15,000 km without any major failure. Another, experimental model vehicle with a rotary distributor pump was developed and received its license plate to operate on public roads.
Technical Paper

Combustion Radicals Observation of DME Engine by Spectroscopic Method

2002-03-04
2002-01-0863
For better understanding of the in-cylinder combustion characteristics of DME, combustion radicals of a direct injection DME-Fueled compression ignition engine were observed using a spectroscopic method. In this initial report, the emission intensity of OH, CH, CHO, C2 and NO radicals was measured using a photomultiplier. These radicals could be measured with wavelength resolution (half-width) of about 3.3 nm. OH and CHO radicals appeared first, and then CH radical emission was detected. After that, the combustion radicals were observed using a high-speed image intensified video camera. C2 and CH radicals were able to observe roughly as images. However, the emission intensity of DME combustion was not strong enough to take OH, CHO and NO radical images. CH radical combustion occurred near the chamber wall and burned like a ring, as combustion progress, indicating active heat release occurred near the chamber wall.
Technical Paper

Spray and Exhaust Emission Characteristics of a Biodiesel Engine Operating with the Blend of Plant Oil and DME

2002-03-04
2002-01-0864
As an effective method to solve the global warming and the energy crisis, the research has been carried out for the adaptability of plant oil as an alternative fuel for Diesel engine. But there are the problems of engine performance and exhaust emissions owing to the high viscosity and low volatility, when the plant oil is used as a fuel. In order to eliminate these problems, spray characteristics of the DME (Dimethyl ether) blended plant oil has been examined by using the image processing based on the shadowgraph methodology. Results show that the optimum mixing ratio of the blend is about 50:50 (by weight %). Thereafter, experiments have been conducted with a DI Diesel engine using the DME blended plant oil, and compared the exhaust emissions with Diesel, DME and transesterified fuel operation. From the results, it can be concluded that the combustion characteristics of DME blended plant oil are comparable to Diesel fuel.
Technical Paper

Investigation of the Combustion Process of a DI CI Engine Fueled with Dimethyl Ether

2001-09-24
2001-01-3504
Dimethyl Ether (DME) is one of the major candidates for the next generation fuel for compression ignition (CI) engines. It has good self-ignitability and would not produce particulate, even at rich conditions. DME has proved to be able to apply to ordinary diesel engines with minimal modifications, but its combustion characteristics are not completely understood. In this study, the behavior of a DME spray and combustion process of a direct injection CI engine fueled with DME was investigated by combustion observation and in-cylinder gas sampling. To distinguish evaporated and non-evaporated zones of a spray, direct and schlieren imaging were carried out. The sampled gas from a DME spray was analyzed by gas chromatography, and the major intermediate product histories during ignition period were analyzed.
Technical Paper

Performance and Emissions of a DI Diesel Engine Operated with LPG and Ignition Improving Additives

2001-09-24
2001-01-3680
This research investigated the performance and emissions of a direct injection (DI) Diesel engine operated on 100% butane liquid petroleum gas (LPG). The LPG has a low cetane number, therefore di-tertiary-butyl peroxide (DTBP) and aliphatic hydrocarbon (AHC) were added to the LPG (100% butane) to enhance cetane number. With the cetane improver, stable Diesel engine operation over a wide range of the engine loads was possible. By changing the concentration of DTBP and AHC several different LPG blended fuels were obtained. In-cylinder visualization was also used in this research to check the combustion behavior. LPG and only AHC blended fuel showed NOX emission increased compared to Diesel fuel operation. Experimental result showed that the thermal efficiency of LPG powered Diesel engine was comparable to Diesel fuel operation. Exhaust emissions measurements showed that NOX and smoke could be considerably reduced with the blend of LPG, DTBP and AHC.
Technical Paper

Spray Characteristics of DME Blended Biodiesel Oil

2001-09-24
2001-01-3636
Spray characteristics of biodiesel oil was investigated as it can be applied to industrial combustion systems, including internal combustion engines. Shadowgraph methodology using Greenfield system was used to take some images of the spray and to measure droplet size. A high speed video camera was also used to take a picture of spray penetration and its angle. From the results, it shows that DME blended biodiesel oil has almost the same droplet size as conventional diesel oil, when the blended DME ratio is over 50% by weight. It is also shown that there exists optimum fuel injection pressure that has minimum droplet size when the ambient gas pressure is constant.
Technical Paper

KIVA Simulation for Mixture Formation Processes in an In-Cylinder Injected LPG SI Engine

2000-10-16
2000-01-2805
This is a preliminary work for the development of a stratified combustion engine using liquefied petroleum gas(LPG) as an alternative fuel. The main objective of this research is to find out the optimizing engine parameters from the viewpoint of mixture formation with the aid of simulation, where the KIVA_ code was used. The combustion characteristics of LPG and gasoline are different because of their different physical properties. Therefore, the numerical simulation was performed for optimizing engine parameters by changing the piston and cylinder geometry, as well as injection conditions. Result showed that geometry of combustion chamber has a great influence on mixture stratification. Also, weaker swirl seems to be better for mixture formation in the vicinity of the spark plug.
Technical Paper

Comparison of Spray Characteristics in Butane and Diesel Fuels by Numerical Analysis

2000-10-16
2000-01-2941
The spray characteristics of n-butane were analyzed numerically using KIVA-3V code and compared with those of diesel under the same boundary conditions. The transient behavior of hollow cone spray was calculated not only in a constant volume chamber under various ambient conditions, but also in a premixed compression ignition engine. The spray characteristics were evaluated in terms of spray tip penetration and droplet size distribution. Various atomization sub-models such as TAB, Wave breakup and Wave-KH (Kelvin-Helmholtz) model were implemented in the code and validated by comparison with experimental data. The results show that mixture formation for butane proceeds faster than diesel fuel primarily due to a higher evaporation rate caused by butane's higher diffusivity in air. Furthermore, in a premixed compression ignition engine, the mixture of butane becomes more homogeneous than diesel by the end of compression stroke.
Technical Paper

The Prediction of Autoignition in a DME Direct Injection Diesel Engine

2000-06-19
2000-01-1827
The ignition delay under various temperature and pressure conditions considering volumetric change is investigated both by experiments and simulation to give some basic data of ignition delay for a DME DI diesel engine. The combustion process in a DME direct injected diesel engine was also observed to help understanding of the difference between DME combustion and that of a diesel fuel. For DME fuel, it was clear that the luminous flame duration is much shorter than that of diesel fuel. The calculated results of ignition delay for high equivalence(ϕ =0.4 in this study) showed good accord qualitatively to those of measured at wide range of temperature and pressure conditions investigated in this work. There exists the negative temperature coefficient region near the temperature of 800K. This study shows basic guideline for optimal injection timing for DME fueled compression ignition engines.
Technical Paper

Effects of Injection Conditions on Mixture Formation Process in a Premixed Compression Ignition Engine

2000-06-19
2000-01-1831
The mixture formation process in a premixed compression ignition engine was numerically analyzed. This study aimed to find out effective injection conditions for lean mixture formation with high homogeneity, since the NOx and soot emissions in the engine are closely related to the mixture homogeneity. To calculate fuel spray behavior, a practical computer code GTT (Generalized Tank and Tube) was employed. In a model for the premixed compression ignition engine, the effects of injection parameters, such as injection timing, initial droplet size, spray angle, injection velocity, nozzle type (pintle and hole) and injection position / direction, on the mixture homogeneity near ignition timing (or TDC) were investigated. To evaluate the homogeneity of the mixture, an index was defined based on the spatial distribution of fuel mass fraction. The fuel vapor mass fractions as well as the homogeneity indices, obtained as a function of time, were compared under various boundary conditions.
Technical Paper

Conversion of Nitric Oxide to Nitrogen Dioxide Using Hydrogen Peroxide

2000-06-19
2000-01-1931
Detailed chemical kinetic model of hydrogen peroxide (H2O2) into diesel exhaust gas has been executed to investigate its effect on the removal of nitric oxide(NO) by changing exhaust gas temperature and H2O2 addition amount. Flux analysis has also been done to clarify which reaction mainly affects NO-to-NO2 conversion. From the results of this study, it is shown that the optimal temperature condition to maximize the removal of NO exists near at 500K for OH addition condition, while that for H2O2 addition exists near at 800K. It is also shown that temperature window for the removal of NO becomes widened as the initial temperature of the exhaust gas increases, and NO-to-NO2 conversion rate decreases in proportion to the concentration of hydrocarbon(HC), although that of the total NOx remains the same level regardless of HC concentration. Finally, it is shown that HO2 + NO → NO2 + OH is mainly responsible for NO-to-NO2 conversion.
Technical Paper

Development of LPG SI and CI Engines for Heavy Duty Vehicles

2000-06-12
2000-05-0166
Development of LPG SI and CI engines for heavy duty vehicles has been carried out. In order to measure the performance and emissions of an LPG lean burn SI engine, the piston cavity, swirl ratio, and propane-butane fuel ratio were varied and tested. Compared to the bathtub and dog dish cavities, the nebula type cavity showed the best performance in terms of cyclic variation and combustion duration. High swirl improved combustion by achieving a high thermal efficiency and low NOx emissions. A feasibility study of an LPG DI diesel engine also has been carried out to study the effectiveness of the selected cetane enhancing additives:Di-tertiary-butyl peroxide (DTBP). When more than 5 wt% DTBP was added to the base fuel, stable engine operation over a wide range of engine loads was possible. The thermal efficiency of LPG fueled operation was found to be comparable to diesel fuel operation at DTBP levels over 5 wt%.
Technical Paper

Chemical Kinetic Study of a Cetane Number Enhancing Additive for an LPG DI Diesel Engine

2000-03-06
2000-01-0193
The oxidation mechanism of DTBP (Di-tertiary-butyl peroxide) and its role in butane oxidation have been investigated, as it pertains to the development of an LPG DI diesel engine. Ignition delay contours were analyzed to investigate the role of DTBP (ϕ≈0.2 to the total oxygen) in butane oxidation. At higher pressure and lower temperature regions, it was apparent that the addition of DTBP significantly enhances the ignition delay of butane, whereas at lower pressures and higher temperatures, this effect diminishes. Results of this study showed that the role of DTBP to enhance the ignition delay of the base fuel is through rapid heat release, rather than by radicals produced by decomposition during the base fuel ignition delay. Formaldehyde is a principal species involved in reactions for heat release in the higher pressure lower temperature region, comparable to diesel engine operating conditions.
Technical Paper

Effects of Initial In-Cylinder Flow Field on Mixture Formation in a Premixed Compression Ignition Engine

2000-03-06
2000-01-0331
To find more effective lean mixture preparation methods for smokeless and low NOx combustion, a numerical study of the effects of in-cylinder flow field before injection on mixture formation in a premixed compression ignition engine was conducted. Premixed compression ignition combustion is a very attractive method to reduce both NOx and soot emissions, but it still has some problems, such as high HC and CO emissions. In case of early direct injection, it is important to avoid wall wetting by spray impingement, which can cause higher HC and CO emissions. Since it is not easy to examine the effects of initial flow and injection parameters on mixture formation over the wide range by practical engine tests, a computer program named “GTT (Generalized Tank and Tube)” code was used to simulate the in-cylinder phenomena before autoignition.
Technical Paper

Development of an LPG DI Diesel Engine Using Cetane Number Enhancing Additives

1999-10-25
1999-01-3602
A feasibility study of an LPG DI diesel engine has been carried out to study the effectiveness of two selected cetane enhancing additives: Di-tertiary-butyl peroxide (DTBP) and 2-Ethylhexyl nitrate (EHN). When more than either 5 wt% DTBP or 3.5 wt% 2EHN was added to the base fuel (100 % butane), stable engine operation over a wide range of engine loads was possible (BMEPs of 0.03 to 0.60 MPa). The thermal efficiency of LPG fueled operation was found to be comparable to diesel fuel operation at DTBP levels over 5 wt%. Exhaust emissions measurements showed that NOx and smoke levels can be significantly reduced using the LPG+DTBP fuel blend compared to a light diesel fuel at the same experimental conditions. Correlations were derived for the measured ignition delay, BMEP, and either DTBP concentration or cetane number. When propane was added to a butane base fuel, the ignition delay became longer.
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